I'm using the 2-D Bar in Insert Tab. It is showing the chart just like this. Able to show the "Data Labels"(Ouside End) through "Add Chart Element". But if you see the image properly, you'll come to know that the Data Labels are in number format and the "Primary Vertical Axes" are in Percentage format. How to do that?
If you want to show a value of 40 as 40% ( unlike a genuine percentage value where 40% will actually be 0.4 ) , all you have to do is choose a Custom Format of 0"%".